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Graphene: A new way of thinking about materials

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Graphene was one of the breakthrough science stories of the new millennium. Hailed as a wonder material of the future, its remarkable physical properties have transformed the way we think about materials.

First isolated at the University of Manchester in 2003 and announced in 2004 by a team led by Andre Geim and Kostya Novoselov, Graphene is the first single-layer material ever discovered. 

At only one atom thick it is the thinnest material possible, yet it is also the strongest—200 times stronger than steel. It’s flexible, transparent and conducts electricity and heat incredibly well, giving this small material huge potential.

The isolation of graphene made a huge splash in science media in the 2010s because it has so many outstanding properties, and speculation about some of the potential applications for this wonder material ran wild.

Two men sat in a laboratory Credit: © Nobel Media AB, Photo Yana Audas
Andre Geim (right) and Kostya Novoselov (left), 2010.

What is graphene?

Graphene is a two-dimensional crystal sheet of carbon atoms, arranged in a hexagonal lattice, so through a very powerful microscope, it looks a bit like chicken wire.

Microscopic close up of graphene, a black and white hexagonal structure Credit: Sarah Haigh, University of Manchester and Quentin Ramasse, EPSRC SuperSTEM Laboratory, Daresbury
Scanning transmission electron microscope image showing the hexagonal atomic structure of graphene.

Graphene is a nanomaterial—it is really, really small. A one millimetre-thick piece of ordinary graphite is made up of 3 million layers of graphene stacked on top of one another. A sheet of graphene is just one of these layers.  

Before it was first isolated, it was already known that graphite was made up of incredibly thin sheets of carbon atoms, and painstaking attempts to get down to that elusive single sheet go back more than a century. Scientists predicted that a single layer of carbon atoms would have fascinating properties, but suspected that it couldn’t possibly be stable. In 2004, a small group of scientists at the University of Manchester proved otherwise.

How was graphene isolated?

Since 1859 scientists had been trying to  achieve a single layer using chemical and mechanical methods involving expensive and specialised equipment. However, when a single sheet of graphene was finally isolated, it was done using a cheap and familiar piece of equipment—ordinary sticky tape.

In 2004 at the University of Manchester, Andre Geim and Konstantin Novoselov found a reliable and cheap method for obtaining monolayer graphene flakes from graphite, using this tape dispenser. The pair were awarded the Nobel Prize for Physics in 2010 for 'groundbreaking experiments regarding the two-dimensional material graphene'.
Science Museum Group Collection More information about In 2004 at the University of Manchester, Andre Geim and Konstantin Novoselov found a reliable and cheap method for obtaining monolayer graphene flakes from graphite, using this tape dispenser. The pair were awarded the Nobel Prize for Physics in 2010 for 'groundbreaking experiments regarding the two-dimensional material graphene'.

Sticky tape was already used to clean samples of graphite ready for experiments and examination by stripping off the top layer to expose the clean graphite beneath. The light bulb moment came when Andre and Kostya’s group wondered if, when they were throwing away the used pieces of sticky tape with graphite residue on them, they might in fact be throwing away graphene. As the anecdote goes, they fished a used piece of tape back out of the bin, put it under a microscope, and were delighted to see really thin flakes of graphite right there on the tape. Peeling and re-peeling made it possible to get right down to transparent films of graphene.

Largely crystalline graphite from the Elswick Furnaces, Newcastle-on-Tyne, communicated by A. Noble, 1867.
Science Museum Group Collection More information about Largely crystalline graphite from the Elswick Furnaces, Newcastle-on-Tyne, communicated by A. Noble, 1867.

The actual sticky tape dispenser used in that story was donated to the Science and Industry Museum by Kostya Novoselov in 2006, and is shown above. It’s a fascinating object because it is so familiar and ordinary, yet it was pivotal to a Nobel Prize-winning breakthrough in materials science. It’s a prime example of the sort of everyday equipment that is part of a science story, but often lost over time precisely because it is so mundane. As Kostya has said, ‘Science should be fun and you don’t always need to do expensive multi-million-dollar experiments to be on the cutting edge of research,’ a point that this sticky tape dispenser really emphasises. 

But isolating a single sheet of graphene was just the start.

Testing graphene

Graphene opened up a whole new world of scientific exploration into single-layer materials. The hard work began immediately after Andre and Kostya isolated graphene. They did extensive experiments and research to investigate the electrical properties of graphene and went on to win a Nobel Prize for the publication of their research.

Geim and Novoselov conducted experiments in their lab at the University of Manchester to explore the electrical properties of graphene. They found that graphene flakes can be used as transistors. They made hand-made circuits like this one, then more precisely made lithographically printed circuits.
Science Museum Group Collection More information about Geim and Novoselov conducted experiments in their lab at the University of Manchester to explore the electrical properties of graphene. They found that graphene flakes can be used as transistors. They made hand-made circuits like this one, then more precisely made lithographically printed circuits.

Using graphene

One of the biggest challenges of applying graphene to commercial products is how to produce industrial scale quantities of it. Manchester remains at the centre of graphene research and scientists at the National Graphene Institute are developing different methods of producing graphene aside from using sticky tape, including chemical deposition. 

Once it became possible to make graphene at scale, the race was on to find commercial applications for the new material. Some other early uses were to enhance the durability of paint, or make lightbulbs use less energy and last longer.

'The Graphene Light Bulb'. This was the first commercially available product available in the UK using graphene.
Science Museum Group Collection More information about 'The Graphene Light Bulb'. This was the first commercially available product available in the UK using graphene.

Graphene is stronger than steel yet lightweight and flexible, making it a good candidate material for clothing designed to be hard-wearing.

Graphene jacket by Vollebak, made in Ho Chi Minh City, Vietnam, 2023. Material made in Italy.
Image credit: Vollebak More information about Graphene jacket by Vollebak, made in Ho Chi Minh City, Vietnam, 2023. Material made in Italy.

A greener graphene future

Graphene's unique properties have inspired scientists and engineers to imagine game-changing new technologies. It’s the most conductive material discovered, giving it great potential for electronics applications, and because it’s also stable and non-reactive, it could have medical uses. It has even been imagined that it could one day enable science fiction-like technology, from nano robots to cyborg brain implants.

The most exciting and more realistic hope for graphene is that its extraordinary properties could play an important role in reducing our impact on the Earth's climate.

In 2018, the Graphene Engineering Innovation Centre (GEIC) opened at the University of Manchester. Whereas the Manchester-based National Graphene Institute features academic-led research in partnership with industry, the GEIC is industry-led and focuses on innovation and practical applications.

One of four test samples of concrete enhanced with graphene, tested at the Graphene Engineering Innovation Centre (GEIC), University of Manchester, by Dr Lisa Scullion, 2021.
Science Museum Group Collection More information about One of four test samples of concrete enhanced with graphene, tested at the Graphene Engineering Innovation Centre (GEIC), University of Manchester, by Dr Lisa Scullion, 2021.

A great example of the world-changing impact graphene could have is the way it could reduce the carbon dioxide emissions caused by concrete production. Production of cement for concrete in the building industry is one of the leading causes of global carbon dioxide emissions. The addition of up to 1% of graphene strengthens concrete by around 30% compared to standard concrete, meaning significantly less is needed to achieve the equivalent structural performance, reducing carbon footprint and costs.

At the Science and Industry Museum, we will continue to follow the story of graphene and share it with our visitors. It certainly has an exciting and open-ended future.